S-[(2-溴苯基)甲基] 乙硫醇

反应条件: temp:0.00; pressure:0.00; stir:

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: To a solution of 2-bromo-benzyl bromide (1 ml, Aldrich 187070) in acetone was added potassium thioacetate (0.9 g, Aldrich 241776) and the mixture refluxed for 2 hr. The reaction mixture was purified on a plug of silica eluting through with further acetone to give thioacetic acid S-(2-bromo-benzyl) ester (1.57 g) 1H-NMR (400 MHz, CDCl3): 2.34 (3H, s), 4.24 (2H, s), 7.09-7.14 (1H, dt), 7.23-7.27 (1H, dt), 7.44-7.46 (1H, dd), 7.54-7.56 (1H, dd). the mixture refluxed for 2 hr The reaction mixture was purified on a plug of silica eluting through with further acetone

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: To a solution of 2-bromo-benzyl bromide (1 ml, Aldrich 187070) in acetone was added potassium thioacetate (0.9 g, Aldrich 241776) and the mixture refluxed for 2 hr. The reaction mixture was purified on a plug of silica eluting through with further acetone to give thioacetic acid S-(2-bromo-benzyl) ester (1.57 g) 1H-NMR (400 MHz, CDCl3): 2.34 (3H, s), 4.24 (2H, s), 7.09-7.14 (1H, dt), 7.23-7.27 (1H, dt), 7.44-7.46 (1H, dd), 7.54-7.56 (1H, dd). the mixture refluxed for 2 hr The reaction mixture was purified on a plug of silica eluting through with further acetone

反应条件: temp:0.00; pressure:0.00; stir:

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: To a solution of 2-bromo-benzyl bromide (1 ml, Aldrich 187070) in acetone was added potassium thioacetate (0.9 g, Aldrich 241776) and the mixture refluxed for 2 hr. The reaction mixture was purified on a plug of silica eluting through with further acetone to give thioacetic acid S-(2-bromo-benzyl) ester (1.57 g) 1H-NMR (400 MHz, CDCl3): 2.34 (3H, s), 4.24 (2H, s), 7.09-7.14 (1H, dt), 7.23-7.27 (1H, dt), 7.44-7.46 (1H, dd), 7.54-7.56 (1H, dd). the mixture refluxed for 2 hr The reaction mixture was purified on a plug of silica eluting through with further acetone