3-(己氧基)丙胺

反应条件: temp:140.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: A mixture of trans-stilbene oxide (1.96 g, 0.010 mol) and 3-hexyloxypropylamine (1.75 g, 0.011 mol) was heated at 140° C. for 6 hours. After standing at ambient temperature for 44 hours, the reaction mixture was dissolved in acetone (10 mL) and the solution poured into water (150 mL). The light brown oil that separated from solution solidified on standing for 1 hour. The solid was collected and dried on absorbent paper for 18 hours. The solid was then triturated in isooctane (soluble) and the solution chilled to obtain a solid that was collected, washed with cold isooctane, and dried under ambient conditions to obtain 1.20 g (34%) of the product; mp 67°-69° C. The light brown oil that separated from solution on standing for 1 hour The solid was collected dried on absorbent paper for 18 hours The solid was then triturated in isooctane (soluble) the solution chilled to obtain a solid that was collected washed with cold isooctane dried under ambient conditions

反应条件: temp:140.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: A mixture of trans-stilbene oxide (1.96 g, 0.010 mole) and 3-hexyloxypropylamine (1.75 g, 0.011 mole) was heated at 140° C. for 6 hours. After standing at ambient temperature for 44 hours, the reaction mixture was dissolved in acetone (10 ml) and the solution poured into water (150 ml). The light brown oil which separated from solution solidified on standing for 1 hour. The solid was collected and dried on absorbent paper for 18 hours. The solid was then triturated in isooctane (soluble) and the solution chilled to obtain a solid which was collected, washed with cold isooctane, and dried under ambient conditions to obtain 1.20 g (34%) of the product, m.p. 67°-69° C. The light brown oil which separated from solution on standing for 1 hour The solid was collected dried on absorbent paper for 18 hours The solid was then triturated in isooctane (soluble) the solution chilled to obtain a solid which was collected washed with cold isooctane dried under ambient conditions