N,N',N'-三甲基己烷-1,6-二胺

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: as well as polyamides resulting from terephthalic acid and/or isophthalic acid and trimethyl hexamethylene diamine, polyamides resulting from adipic acid and meta xylylenediamines, polyamides resulting from adipic acid, azelaic acid and 2,2-bis(p-aminocyclohexyl)propane and polyamides resulting from terephthalic acid and 4,4'-diamino-dicyclohexylmethane.

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: as well as polyamides resulting from terephthalic acid and/or isophthalic acid and trimethyl hexamethylene diamine, polyamides resulting from adipic acid and meta xylylenediamines, polyamides resulting from adipic acid, azelaic acid and 2,2-bis(p-aminocyclohexyl)propane and polyamides resulting from terephthalic acid and 4,4'-diamino-dicyclohexylmethane.

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: About 37.93 g (0.24 mol) trimethyl-hexamethylene-diamine and about 0.6 g (0.0024 mol) copper sulfate pentahydrate were dissolved in about 400 mL of methanol. About 26.4 g (0.24 mol) of catechol (chemical name 1,2-dihydroxybenzene) acting as both the quinone precursor and catalyst was added to the reactant mixture. A gentle stream of oxygen at a flow rate of about 50 cc/min was then passed through the reaction mixture for about three hours, while maintaining the reaction temperature around 20°-25 ° C. At the end of three hours the oxygen supply was cut off and the reaction mixture was concentrated under vacuum using a rotary evaporator. The o-benzoquinone-trimethyl-hexamethylene-diamine polymer was precipitated in excess water, washed extensively and dried under vacuum for about 6 hours at a temperature of about 30° C. was added to the reactant mixture while maintaining the reaction temperature around 20°-25 ° C At the end of three hours the reaction mixture was concentrated under vacuum a rotary evaporator The o-benzoquinone-trimethyl-hexamethylene-diamine polymer was precipitated in excess water washed extensively dried under vacuum for about 6 hours at a temperature of about 30° C.

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: as well as polyamides resulting from terephthalic acid and/or isophthalic acid and trimethyl hexamethylene diamine, polyamides resulting from adipic acid and meta xylylenediamines, polyamides resulting from adipic acid, azelaic acid and 2,2-bis(p-aminocyclohexyl)propane and polyamides resulting from terephthalic acid and 4,4'-diamino-dicyclohexylmethane.