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2-甲基戊酸甲酯（CAS 2177-77-7）的产品身份、结构标识及相关反应资料，供化学中间体检索、研发和采购评估使用。
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11 条反应 · 11 篇文献
反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
实验步骤: Prepared analogously as described for example C5 using 3,4-dimethoxybenzoyl chloride, methyl 2-methylpentanoate and hydrazine hydrate as starting compounds. Prepared analogously
来源 ID: ord-88978b5d553e4a598e224fe5af179bb9反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
实验步骤: Prepared analogously as described for the example C5 using 3,4-dimethoxybenzoyl chloride, methyl 2-methylpentanoate and hydrazine hydrate as starting compounds. Prepared analogously
来源 ID: ord-80db82deb94b46b1ada66b6297f68b34反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
实验步骤: Prepared analogously as described for the example C5 using 3,4-dimethoxybenzoyl chloride, methyl 2-methylpentanoate and hydrazine hydrate as starting compounds. Prepared analogously
来源 ID: ord-80db82deb94b46b1ada66b6297f68b34实验步骤: 投料: 2-甲基戊酸甲酯（5g）溶于超干THF(100ml),降温至-20℃，缓慢滴加LDA（19.20 ml），反应20min，快速加入HMPA（6.88g），在0℃下搅拌5 min，在0℃下滴加碘乙烷（6.58g）。滴加完后升温至室温反应1h。\n监测: GCMS监测，结果显示有产物生成\n后处理: 用饱和氯化铵（40 ml）淬灭反应，加入乙酸乙酯（80 ml*2）萃取，合并有机相并用饱和食盐水洗涤（100 ml*1），减压蒸馏除去溶剂得到黄色油状粗品5.8g，直接用于下一步。
来源 ID: 907-M-C4X-116612-R1S1B1实验步骤: 02-16 16:33: 2-甲基戊酸甲酯（9g，1eq）溶于超干THF（230ml），降温至-20℃，缓慢滴加LDA（34.57ml,1eq），反应20min，快速加入HMPA（12.03ml，1eq），在0℃搅拌5min，在0℃下滴加碘丙烷（6.08ml，1.1eq）。加完升至室温反应1小时。送GCMS，有产物碎片。TLC用PE/EA=5/1。 后处理：用饱和NH4Cl（100ml）淬灭，用EA萃取。有机相在用饱和食盐水洗1次，干燥浓缩得粗样15g。不处理直接投下一步。
来源 ID: 583-M-C4X-116612-R1S1B2实验步骤: 01-28 10:21: 2-甲基戊酸甲酯（1g，1eq）溶于超干THF（25ml），降温至-20℃，缓慢滴加LDA（4.22ml,1.1eq），反应20min，快速加入HMPA（1.34ml，1eq），在0℃搅拌5min，在0℃下滴加碘丙烷（0.615ml，1eq）。加完升至室温反应1小时。送GCMS，有产物碎片。TLC用PE/EA=5/1。 后处理：用饱和NH4Cl（10ml）淬灭，用EA萃取。有机相在用饱和食盐水洗1次，干燥浓缩得粗样1.2g。不处理直接投下一步。
来源 ID: 583-M-C4X-116612-R1S1B1反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
实验步骤: Prepared analogously as described for the example C5 using 3,4-dimethoxybenzoyl chloride, methyl 2-methylpentanoate and hydrazine hydrate as starting compounds. Prepared analogously
来源 ID: ord-4889b6130e104b869f7c39dc73138fc2反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
实验步骤: Prepared analogously as described for example C5 using 3,4-dimethoxybenzoyl chloride, methyl 2-methylpentanoate and hydrazine hydrate as starting compounds. Prepared analogously
来源 ID: ord-88978b5d553e4a598e224fe5af179bb9反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
实验步骤: Prepared analogously as described for the example C5 using 3,4-dimethoxybenzoyl chloride, methyl 2-methylpentanoate and hydrazine hydrate as starting compounds. Prepared analogously
来源 ID: ord-80db82deb94b46b1ada66b6297f68b34反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
实验步骤: Prepared analogously as described for example C5 using 3,4-dimethoxybenzoyl chloride, methyl 2-methylpentanoate and hydrazine hydrate as starting compounds. Prepared analogously
来源 ID: ord-7534185c0d5e44da817b361b82fa6165反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.
实验步骤: Prepared analogously as described for example C5 using 3,4-dimethoxybenzoyl chloride, methyl 2-methylpentanoate and hydrazine hydrate as starting compounds. Prepared analogously
来源 ID: ord-0a816d3196ef4d538213523ae468359bPubChem References
以下资料来自该化合物的公开数据库参考记录。