2-(4,4-二甲基戊烷-2-基)-5,7,7-三甲基-辛烷-1-醇

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The same reaction as in Reference Example 1 was carried out under the same conditions except that the 5,7,7-trimethyl-2-(1,3,3-trimethylbutyl) octanol in Reference Example 1 was replaced by 2-heptylundecanol, whereupon 65 g (yield: 80%) of 2-heptylundecyl glycidyl ether was obtained. The same reaction as in Reference Example 1

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The same reaction as in Reference Example 1 was carried out under the same conditions except that the 5,7,7-trimethyl-2-(1,3,3-trimethylbutyl) octanol in Reference Example 1 was replaced by 2-heptylundecanol, whereupon 65 g (yield: 80%) of 2-heptylundecyl glycidyl ether was obtained. The same reaction as in Reference Example 1

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The same reaction as in Reference Example 1 was carried out under the same conditions except that the 5,7,7-trimethyl-2-(1,3,3-trimethylbutyl) octanol in Reference Example 1 was replaced by 2-heptylundecanol, whereupon 65 g (yield: 80%) of 2-heptylundecyl glycidyl ether was obtained. The same reaction as in Reference Example 1

反应条件: temp:-10.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: With nitrogen substitution, 540 ml of toluene and 138.0 grams (0.9 moles) of phosphorus oxychloride were added and cooled to −10 degrees C. To this mixture, a solution of 243.5 grams (0.9 moles; 1.0 in molar ratio) of 2-(1,3,3-trimethyl-n-butyl)-5,7,7-trimethyl-n-octanol and 91.1 grams (0.9 moles) of triethylamine was dripped, and the mixture was reacted for 12 hours at 0 degrees C. The mixture was then heated to 25 degrees C., and a triethylamine hydrochloride was removed by filtering to obtain 1003.9 grams of a toluene solution of [2-(1,3,3-trimethyl-n-butyl)-5,7,7-trimethyl-n-octyl] dichlorophosphate (34.7% in concentration). the mixture was reacted for 12 hours at 0 degrees C The mixture was then heated to 25 degrees C , and a triethylamine hydrochloride was removed by filtering

反应条件: temp:-10.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: With nitrogen substitution, 540 ml of toluene and 138.0 grams (0.9 moles) of phosphorus oxychloride were added and cooled to −10 degrees C. To this mixture, a solution of 243.5 grams (0.9 moles; 1.0 in molar ratio) of 2-(1,3,3-trimethyl-n-butyl)-5,7,7-trimethyl-n-octanol and 91.1 grams (0.9 moles) of triethylamine was dripped, and the mixture was reacted for 12 hours at 0 degrees C. The mixture was then heated to 25 degrees C., and a triethylamine hydrochloride was removed by filtering to obtain 1003.9 grams of a toluene solution of [2-(1,3,3-trimethyl-n-butyl)-5,7,7-trimethyl-n-octyl]dichlorophosphate (34.7% in concentration). the mixture was reacted for 12 hours at 0 degrees C The mixture was then heated to 25 degrees C , and a triethylamine hydrochloride was removed by filtering

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The same reaction as in Reference Example 1 was carried out under the same conditions except that the 5,7,7-trimethyl-2-(1,3,3-trimethylbutyl) octanol in Reference Example 1 was replaced by 2-heptylundecanol, whereupon 65 g (yield: 80%) of 2-heptylundecyl glycidyl ether was obtained. The same reaction as in Reference Example 1