乙醇合三氯乙醛

反应条件: temp:0.00; pressure:0.00; stir:

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The following materials were charged to the reaction vessel: anhydrous diethylamine (292 grams); ethyl acrylate (200 grams); phenothiazine (1.0 gram); and p-methoxyphenol (1.0 gram). This mixture was heated at reflux (about 56°-60°C.) for 24 hours. At the end of this period, unreacted amine was removed by distillation. The product was recovered at 80°-81°C. and 10 mm. mercury pressure in a yield of 96 percent. The product is designated herein as Amine Catalyst IX and has the formula, (C2H5)2N-CH2CH2 -C(O)OC2H5, as verified analytically by infrared spectroscopy. The following materials were charged to the reaction vessel This mixture was heated at reflux (about 56°-60°C.) for 24 hours At the end of this period, unreacted amine was removed by distillation The product was recovered at 80°-81°C.

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The following materials were charged to the reaction vessel: anhydrous diethylamine (292 grams); ethyl acrylate (200 grams); phenothiazine (1.0 gram); and p-methoxyphenol (1.0 gram). This mixture was heated at reflux (about 56°-60° C.) for 24 hours. At the end of this period, unreacted amine was removed by distillation. The product was recovered at 80°-81° C. and 10 mm. mercury pressure in a yield of 96 percent. The product is designated herein as Amine Catalyst IX and has the formula, (C2H5)2N-Ch2CH2 -C(O)OC2H5, as verified analytically by infrared spectroscopy. The following materials were charged to the reaction vessel This mixture was heated at reflux (about 56°-60° C.) for 24 hours At the end of this period, unreacted amine was removed by distillation The product was recovered at 80°-81° C.

反应条件: temp:58.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The following materials were charged to the reaction vessel: anhydrous diethylamine (292 grams); ethyl acrylate (200 grams); phenothiazine (1.0 gram); and p-methoxyphenol (1.0 gram). This mixture was heated at reflux (about 56-60° C.) for 24 hours. At the end of this period, unreacted amine was removed by distillation. The product was recovered at 80°-81° C. and 10 mm. mercury pressure in a yield of 96 percent. The product is designated herein as Amine Catalyst IX and has the formula, (C2H5)2N--CH2CH2 -C(O)OC2H5, as verified analytically by infrared spectroscopy. The following materials were charged to the reaction vessel This mixture was heated At the end of this period, unreacted amine was removed by distillation The product was recovered at 80°-81° C.

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The following materials were charged to the reaction vessel: anhydrous diethylamine (292 grams); ethyl acrylate (200 grams); phenothiazine (1.0 gram); and p-methoxyphenol (1.0 gram). This mixture was heated at reflux (about 56°-60°C.) for 24 hours. At the end of this period, unreacted amine was removed by distillation. The product was recovered at 80°-81°C. and 10 mm. mercury pressure in a yield of 96 percent. The product is designated herein as Amine Catalyst IX and has the formula, (C2H5)2N-CH2CH2 -C(O)OC2H5, as verified analytically by infrared spectroscopy. The following materials were charged to the reaction vessel This mixture was heated at reflux (about 56°-60°C.) for 24 hours At the end of this period, unreacted amine was removed by distillation The product was recovered at 80°-81°C.

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The following materials were charged to the reaction vessel: anhydrous diethylamine (292 grams); ethyl acrylate (200 grams); phenothiazine (1.0 gram); and p-methoxyphenol (1.0 gram). This mixture was heated at reflux (about 56°-60° C.) for 24 hours. At the end of this period, unreacted amine was removed by distillation. The product was recovered at 80°-81° C. and 10 mm. mercury pressure in a yield of 96 percent. The product is designated herein as Amine Catalyst IX and has the formula, (C2H5)2N-Ch2CH2 -C(O)OC2H5, as verified analytically by infrared spectroscopy. The following materials were charged to the reaction vessel This mixture was heated at reflux (about 56°-60° C.) for 24 hours At the end of this period, unreacted amine was removed by distillation The product was recovered at 80°-81° C.

反应条件: temp:58.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The following materials were charged to the reaction vessel: anhydrous diethylamine (292 grams); ethyl acrylate (200 grams); phenothiazine (1.0 gram); and p-methoxyphenol (1.0 gram). This mixture was heated at reflux (about 56-60° C.) for 24 hours. At the end of this period, unreacted amine was removed by distillation. The product was recovered at 80°-81° C. and 10 mm. mercury pressure in a yield of 96 percent. The product is designated herein as Amine Catalyst IX and has the formula, (C2H5)2N--CH2CH2 -C(O)OC2H5, as verified analytically by infrared spectroscopy. The following materials were charged to the reaction vessel This mixture was heated At the end of this period, unreacted amine was removed by distillation The product was recovered at 80°-81° C.