C9-11 醇

反应条件: temp:0.00; pressure:0.00; stir:

反应条件: temp:0.00; pressure:0.00; stir:

反应条件: temp:220.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: A standard 2-liter esterification apparatus was charged with 292 g adipic acid and 727 g isodecyl alcohol. The mixture was heated to reflux, removing water as formed. After 30 minutes of reflux the temperature was 215° C. and 40 ml of water was collected, at which time 0.9 g of catalyst compound ATC-I was added to the flask. The pressure was reduced as needed to maintain the reflux temperature at 220° C. After an additional 45 minutes the water of reaction was collected and the acid number of the residue was measured to be 0.01 mg KOH/g. Heating was discontinued and excess alcohol removed as the pressure was reduced to 20 torr. The reaction mixture was cooled to 170° C., the catalyst was hydrolyzed and the remaining alcohol removed by steam distillation using 100 ml water during 2 hours at 100 torr. The residue was filtered with a No. 1 Whatman paper coated with diatomaceous earth to yield a clear residue product diisodecyl adipate (DIDA) (nD25 =1.4502) having an acid number of 0.05 mg KOH/g and color of 15 APHA. The product remained clear after storage for six months at ambient temperature. The mixture was heated to reflux removing water as formed After 30 minutes of reflux the temperature was 215° C. 40 ml of water was collected, at which time 0.9 g of catalyst compound ATC-I was added to the flask After an additional 45 minutes the water of reaction was collected Heating excess alcohol removed as the pressure The reaction mixture was cooled to 170° C. the remaining alcohol removed by steam distillation during 2 hours The residue was filtered with a No

反应条件: temp:210.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: A standard 1-liter esterification system was charged with 111 g of phthalic anhydride, 284 g of isodecyl alcohol and 0.5 g of catalyst ATC-II. The system was heated to reflux and the temperature was maintained at 210° C. at reduced pressure. At the end of 1.25 hours the water of reaction was collected and the acid number of the residue was measured to be 0.03 mg KOH/g. Heating was discontinued and excess alcohol removed as the pressure was reduced to 100 torr. Adjusting the temperature to 150° C., hydrolysis of the catalyst and removal of remaining alcohol was accomplished by steam distillation using 40 ml water during 35 minutes at 150° C. and 100 torr. After drying for 15 minutes at these conditions the cloudy crude product was cooled to 90° C. and filtered through a No. 1 Whatman paper to yield a clear residue product diisodecyl phthalate (DIDP) (nD25 =1.4850) having an acid number of 0.04 mg KOH/g and a color of 15 APHA. The system was heated to reflux was collected Heating excess alcohol removed as the pressure to 150° C. hydrolysis of the catalyst and removal of remaining alcohol was accomplished by steam distillation during 35 minutes at 150° C. After drying for 15 minutes at these conditions the cloudy crude product was cooled to 90° C. filtered through a No

反应条件: temp:140.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: To 157 g isodecyl alcohol in 200 ml xylene is added 117 g AA, 1.0 g HQ and 2.0Q PTSA. The reaction mixture is heated for 2 hrs. at reflux (140° C) while the water of reaction is collected (17 ml). The reaction mixture is cooled and the xylene removed under reduced pressure to give 250 g isodecyl acrylate. The analytical data for this acrylate is shown below. The reaction mixture is heated for 2 hrs is collected (17 ml) The reaction mixture is cooled the xylene removed under reduced pressure

反应条件: temp:140.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: To 157 g isodecyl alcohol in 200 ml xylene is added 117 g AA, 1.0 g HQ and 2.0Q PTSA. The reaction mixture is heated for 2 hrs. at reflux (140° C) while the water of reaction is collected (17 ml). The reaction mixture is cooled and the xylene removed under reduced pressure to give 250 g isodecyl acrylate. The analytical data for this acrylate is shown below. The reaction mixture is heated for 2 hrs is collected (17 ml) The reaction mixture is cooled the xylene removed under reduced pressure

反应条件: temp:140.02; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: A phenol-free magnesium oleate/carbonate containing about 4.5% magnesium was prepared by the following procedure. A mixture of 529.3 g of oleic acid, 600 g of Shellflex™ 6111 light mineral oil, 400 g of isopropyl alcohol, 350 g of isodecyl alcohol, 400 g of water was heated to 140° F. and 400 g of magnesium hydroxide was added. The neutralization of the acid with the magnesium hydroxide caused the temperature to rise to 167° F. Carbon dioxide gas was passed into the reaction mixture through a subsurface addition tube at a rate of 225 ml/minute for 6 hours, during which time the temperature was gradually raised to 223° F. and 720 ml of a mixture of water and isopropyl alcohol was removed. The temperature was raised to 305° F. and the remaining water was removed with the assistance of the carbon dioxide addition. The carbon dioxide addition was stopped, and the hot reaction mixture was filtered with suction with the assistance of filter aid, giving the overbased magnesium product as a clear light yellow mobile liquid. The product was analyzed to contain 4.5% magnesium by weight. to rise to 167° F was gradually raised to 223° F. 720 ml of a mixture of water and isopropyl alcohol was removed The temperature was raised to 305° F. the remaining water was removed with the assistance of the carbon dioxide addition The carbon dioxide addition the hot reaction mixture was filtered with suction with the assistance of filter aid

反应条件: temp:176.02; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: A phenol-free strontium oleate/carbonate containing about 14% strontium was prepared by the following procedure. A mixture of 413 g of oleic acid, 600 g of Shellflex™ 6111 light mineral oil, 300 g of isodecyl alcohol, 40 g of butyl carbitol, and 4 g of triethylene glycol was heated to 176° F., and 1000 g of strontium hydroxide octahydrate was added. The reaction mixture was heated to 275° F. over a 2.5-hour period, while removing 550 g of water via a Dean-Stark trap with the aid of a nitrogen sparge at 2.0 SCFH. After the rate of water removal slowed, the nitrogen sparge was turned off, and carbon dioxide gas was added to the reaction via a subsurface addition tube at a rate of 450 ml/minute, and the water formed was continually removed. After 7 hours of carbon dioxide addition at 250-275° F., the carbon dioxide was turned off, the temperature of the reaction was raised to 300° F. and the remaining water was removed with the assistance of a nitrogen sparge at 2.0 SCFH. The reaction was then filtered hot with suction with the assistance of filter aid, yielding the overbased strontium oleate carbonate as a light yellow, clear mobile liquid. The product was analyzed to contain 14.25% strontium by weight. The reaction mixture was heated to 275° F. over a 2.5-hour period while removing 550 g of water via a Dean-Stark trap with the aid of a nitrogen sparge at 2.0 SCFH After the rate of water removal the nitrogen sparge carbon dioxide gas was added to the reaction via a subsurface addition tube at a rate of 450 ml/minute the water formed was continually removed After 7 hours of carbon dioxide addition at 250-275° F. the temperature of the reaction was raised to 300° F. the remaining water was removed with the assistance of a nitrogen sparge at 2.0 SCFH The reaction was then filtered hot with suction with the assistance of filter aid

反应条件: temp:176.02; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: A phenol-free strontium oleate/carbonate containing about 14% strontium was prepared by the following procedure. A mixture of 413 g of oleic acid, 600 g of Shellflex™ 6111 light mineral oil, 300 g of isodecyl alcohol, 40 g of butyl carbitol, and 4 g of triethylene glycol was heated to 176° F., and 1000 g of strontium hydroxide octahydrate was added. The reaction mixture was heated to 275° F. over a 2.5-hour period, while removing 550 g of water via a Dean-Stark trap with the aid of a nitrogen sparge at 2.0 SCFH. After the rate of water removal slowed, the nitrogen sparge was turned off, and carbon dioxide gas was added to the reaction via a subsurface addition tube at a rate of 450 ml/minute, and the water formed was continually removed. After 7 hours of carbon dioxide addition at 250-275° F., the carbon dioxide was turned off, the temperature of the reaction was raised to 300° F. and the remaining water was removed with the assistance of a nitrogen sparge at 2.0 SCFH. The reaction was then filtered hot with suction with the assistance of filter aid, yielding the overbased strontium oleate carbonate as a light yellow, clear mobile liquid. The product was analyzed to contain 14.25% strontium by weight. The reaction mixture was heated to 275° F. over a 2.5-hour period while removing 550 g of water via a Dean-Stark trap with the aid of a nitrogen sparge at 2.0 SCFH After the rate of water removal the nitrogen sparge carbon dioxide gas was added to the reaction via a subsurface addition tube at a rate of 450 ml/minute the water formed was continually removed After 7 hours of carbon dioxide addition at 250-275° F. the temperature of the reaction was raised to 300° F. the remaining water was removed with the assistance of a nitrogen sparge at 2.0 SCFH The reaction was then filtered hot with suction with the assistance of filter aid

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The preparation from 3,5,5-trimethylhexanoic acid and isodecyl alcohol (mixture of methyl branched primary decanols from Hoechst) was analogous to Example 3; colorless liquid of medium viscosity; B.P. (1.3 mbar)=148°-154° C. (1.3 mbar)=148°-154° C.

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The isodecyl ester of 4-carboxypyridazine was prepared using the general method of Example 17 from isodecanol and 4,5-dicarboxypyridazine. The product has a boiling range of 150°-160° C. at 0.4 mm of mercury pressure. The product was evaluated as an extractant for copper by the procedure of Example 1, and the results are listed in Table 1. The results show that this compound has inferior solubility to the corresponding isooctadecyl ester of Example 17.

反应条件: temp:220.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: A standard 2-liter esterification apparatus was charged with 292 g adipic acid and 727 g isodecyl alcohol. The mixture was heated to reflux, removing water as formed. After 30 minutes of reflux the temperature was 215° C. and 40 ml of water was collected, at which time 0.9 g of catalyst compound ATC-I was added to the flask. The pressure was reduced as needed to maintain the reflux temperature at 220° C. After an additional 45 minutes the water of reaction was collected and the acid number of the residue was measured to be 0.01 mg KOH/g. Heating was discontinued and excess alcohol removed as the pressure was reduced to 20 torr. The reaction mixture was cooled to 170° C., the catalyst was hydrolyzed and the remaining alcohol removed by steam distillation using 100 ml water during 2 hours at 100 torr. The residue was filtered with a No. 1 Whatman paper coated with diatomaceous earth to yield a clear residue product diisodecyl adipate (DIDA) (nD25 =1.4502) having an acid number of 0.05 mg KOH/g and color of 15 APHA. The product remained clear after storage for six months at ambient temperature. The mixture was heated to reflux removing water as formed After 30 minutes of reflux the temperature was 215° C. 40 ml of water was collected, at which time 0.9 g of catalyst compound ATC-I was added to the flask After an additional 45 minutes the water of reaction was collected Heating excess alcohol removed as the pressure The reaction mixture was cooled to 170° C. the remaining alcohol removed by steam distillation during 2 hours The residue was filtered with a No