1,2-环氧十六烷

反应条件: temp:120.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 2,5-Dimercapto-1,3,4-thiadiazole (161.3 g, 1.08 mol) and alphapinene (161.3 g, 1.18 mol) were charged to a reaction vessel and cautiously heated to 120° C. (exothermic reaction). The reaction was maintained at 135° C. for one hour. The intermediate product was stripped under vacuum at 135° C. to remove any unreacted pinene and filtered hot. Methanol (200 ml), hexane (150 ml) and water (15 ml) were charged. The hexane layer was removed and discharded. The methanol layer was stripped of methanol by rotary evaporation and the intermediate product residue was mixed with toluene (200 ml) and then extracted with 1M sodium bicarbonate solution (50 ml). The toluene layer was dried over magnesium sulfate and the solvent removed by rotary evaporation. The yield was 134.1 g (0.468 mol) of the purified intermediate, 2-(2-pinanylthio)-5-mercapto-1,3,4-thiadiazole. This product was reacted with 1,2-epoxyhexadecane (112.3 g, 0.468 mol) by charging both reagents and isopropanol (100 ml) and bringing the reaction to reflux. The solvent was then stripped by rotary evaporation to afford the product. (exothermic reaction) The reaction was maintained at 135° C. for one hour was stripped under vacuum at 135° C. to remove any unreacted pinene filtered hot Methanol (200 ml), hexane (150 ml) and water (15 ml) were charged The hexane layer was removed The methanol layer was stripped of methanol by rotary evaporation the intermediate product residue was mixed with toluene (200 ml) extracted with 1M sodium bicarbonate solution (50 ml) The toluene layer was dried over magnesium sulfate the solvent removed by rotary evaporation the reaction to reflux The solvent was then stripped by rotary evaporation to afford the product

反应条件: temp:120.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 2,5-Dimercapto-1,3,4-thiadiazole (161.3 g, 1.08 mol) and alphapinene (161.3 g, 1.18 mol) were charged to a reaction vessel and cautiously heated to 120° C. (exothermic reaction). The reaction was maintained at 135° C. for one hour. The intermediate product was stripped under vacuum at 135° C. to remove any unreacted pinene and filtered hot. Methanol (200 ml), hexane (150 ml) and water (15 ml) were charged. The hexane layer was removed and discharded. The methanol layer was stripped of methanol by rotary evaporation and the intermediate product residue was mixed with toluene (200 ml) and then extracted with 1M sodium bicarbonate solution (50 ml). The toluene layer was dried over magnesium sulfate and the solvent removed by rotary evaporation. The yield was 134.1 g (0.468 mol) of the purified intermediate, 2-(2-pinanylthio)-5-mercapto-1,3,4-thiadiazole. This product was reacted with 1,2-epoxyhexadecane (112.3 g, 0.468 mol) by charging both reagents and isopropanol (100 ml) and bringing the reaction to reflux. The solvent was then stripped by rotary evaporation to afford the product. (exothermic reaction) The reaction was maintained at 135° C. for one hour was stripped under vacuum at 135° C. to remove any unreacted pinene filtered hot Methanol (200 ml), hexane (150 ml) and water (15 ml) were charged The hexane layer was removed The methanol layer was stripped of methanol by rotary evaporation the intermediate product residue was mixed with toluene (200 ml) extracted with 1M sodium bicarbonate solution (50 ml) The toluene layer was dried over magnesium sulfate the solvent removed by rotary evaporation the reaction to reflux The solvent was then stripped by rotary evaporation to afford the product

反应条件: temp:120.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 2,5-Dimercapto-1,3,4-thiadiazole (161.3 g, 1.08 mol) and alphapinene (161.3 g, 1.18 mol) were charged to a reaction vessel and cautiously heated to 120° C. (exothermic reaction). The reaction was maintained at 135° C. for one hour. The intermediate product was stripped under vacuum at 135° C. to remove any unreacted pinene and filtered hot. Methanol (200 ml), hexane (150 ml) and water (15 ml) were charged. The hexane layer was removed and discharded. The methanol layer was stripped of methanol by rotary evaporation and the intermediate product residue was mixed with toluene (200 ml) and then extracted with 1M sodium bicarbonate solution (50 ml). The toluene layer was dried over magnesium sulfate and the solvent removed by rotary evaporation. The yield was 134.1 g (0.468 mol) of the purified intermediate, 2-(2-pinanylthio)-5-mercapto-1,3,4-thiadiazole. This product was reacted with 1,2-epoxyhexadecane (112.3 g, 0.468 mol) by charging both reagents and isopropanol (100 ml) and bringing the reaction to reflux. The solvent was then stripped by rotary evaporation to afford the product. (exothermic reaction) The reaction was maintained at 135° C. for one hour was stripped under vacuum at 135° C. to remove any unreacted pinene filtered hot Methanol (200 ml), hexane (150 ml) and water (15 ml) were charged The hexane layer was removed The methanol layer was stripped of methanol by rotary evaporation the intermediate product residue was mixed with toluene (200 ml) extracted with 1M sodium bicarbonate solution (50 ml) The toluene layer was dried over magnesium sulfate the solvent removed by rotary evaporation the reaction to reflux The solvent was then stripped by rotary evaporation to afford the product

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: Condensation of 1-hexadecene oxide and hexamethylenediamine affords N,N'-(1,6-hexylene)-bis[2-hydroxyhexadecylamine] (I: R= CH3 (CH2)13, R' = H, X= (CH2)6, Z= H).

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: Condensation of 1-hexadecene oxide and hexamethylenediamine affords N,N'-(1,6-hexylene)-bis[2-hydroxyhexadecylamine] (I: R = CH3 (CH2)13, R' = H, X = (CH2)6, Z = H).

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 120 grams of random, internal epoxyhexadecane was placed in a glass-lined autoclave with 40 ml. of 10% H2SO4. The mixture was heated to 150° C. for 3 hours under 300 psi N2. Upon cooling, the product solidified in the autoclave. The aqueous portion was decanted, and the solid was dissolved in hot hexane. The solution was dried over anhydrous, MgSO4, filtered, and cooled. The resulting crystals were removed by filtration to yield approximately 95% of pure random, internal vicinal hexadecane diol. Upon cooling The aqueous portion was decanted the solid was dissolved in hot hexane The solution was dried over anhydrous, MgSO4 filtered cooled The resulting crystals were removed by filtration

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The epoxide (9) (4.8 g, 20 mmoles) as obtained in Example 4-1 was reacted with 7.6 g (40 mmoles) of 2-methylglycerol monotetrahydropyranyl ether in the same manner as Example 1-2 to give 4.58 g (53.2%) of the desired compound (10).

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: Condensation of 1-hexadecene oxide and hexamethylenediamine affords N,N'-(1,6-hexylene)-bis[2-hydroxyhexadecylamin] (I: R = CH3 (CH2)13, R' = H, X = (CH2)6, Z = H).

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: Condensation of 1-hexadecene oxide and hexamethylenediamine affords N,N'-(1,6-hexylene)-bis[2-hydroxyhexadecylamine] (I: R = CH3 (CH2)13, R' = H, X = (CH2)6, Z = H).