2-环己基环己酮

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 1.170 g (6.5 mols) of 2-cyclohexyl-cyclohexanone are reacted with 757.9 g (7.15 mols) of trimethyl orthoformate and 743.6 g (7.15 mols) of anhydrous 2,2-dimethyl-1,3-propanediol in a manner analogous to that in Example 1:

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 1.170 g (6.5 mols) of 2-cyclohexyl-cyclohexanone are reacted with 757.9 g (7.15 mols) of trimethyl orthoformate and 743.6 g (7.15 mols) of anhydrous 2,2-dimethyl-1,3-propanediol in a manner analogous to that in Example 1:

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 1,260 g (7 mols) of 2-cyclohexyl-cyclohexanone are reacted with 816.2 g (7.7 mols) of trimethylorthoformate and 477.4 g (7.7 mols) of anhydrous 1,2-ethanediol in a manner analogous to that in Example 1.

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 2-Cyclohexylcyclohexanone (99 mg, 0.55 mmol) was reacted with tert.-butoxy-bis-(dimethylamino)-methane using in analogous manner the procedure described in example 45a) to give crude title compound (116 mg) as a brown solid which was used directly in the next step. MS ISP (m/e): 236.2 (100) [(M+H)+].

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 1.170 g (6.5 mols) of 2-cyclohexyl-cyclohexanone are reacted with 757.9 g (7.15 mols) of trimethyl orthoformate and 743.6 g (7.15 mols) of anhydrous 2,2-dimethyl-1,3-propanediol in a manner analogous to that in Example 1:

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 1,260 g (7 mols) of 2-cyclohexyl-cyclohexanone are reacted with 816.2 g (7.7 mols) of trimethylorthoformate and 477.4 g (7.7 mols) of anhydrous 1,2-ethanediol in a manner analogous to that in Example 1.