1-甲氧基辛烷

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: Nitrogen gas was introduced downflow to a 1″×18″ 316 s.s. hot tube reactor system containing 67 ml of silicon carbide (SiC) at a total rate of 6.2 ml/min. The hot tube reactor was heated to 450° C. at which time 1-methoxyoctane (MO), obtained from hydrogenation of 1-methoxy-2,7-octadiene, was added downflow at 0.1 ml/min. Under these conditions 1-methoxyoctane was converted to a mixture of 1-octene and mixed internal octenes at 3.3% wt conversion with a selectivity to 1-octene of 10 m % and mixed internal octenes of 90 m %. Nitrogen gas was introduced downflow to a 1″×18″ 316 s

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: Nitrogen gas was introduced downflow to a 1″×18″ 316 s.s. hot tube reactor system containing 67 ml of silicon carbide (SiC) at a total rate of 6.2 ml/min. The hot tube reactor was heated to 450° C. at which time 1-methoxyoctane (MO), obtained from hydrogenation of 1-methoxy-2,7-octadiene, was added downflow at 0.1 ml/min. Under these conditions 1-methoxyoctane was converted to a mixture of 1-octene and mixed internal octenes at 3.3% wt conversion with a selectivity to 1-octene of 10 m % and mixed internal octenes of 90 m %. Nitrogen gas was introduced downflow to a 1″×18″ 316 s

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: Nitrogen gas was introduced downflow to a 1″×18″ 316 s.s. hot tube reactor system containing 67 ml of silicon carbide (SiC) at a total rate of 6.2 ml/min. The hot tube reactor was heated to 450° C. at which time 1-methoxyoctane (MO), obtained from hydrogenation of 1-methoxy-2,7-octadiene, was added downflow at 0.1 ml/min. Under these conditions 1-methoxyoctane was converted to a mixture of 1-octene and mixed internal octenes at 3.3% wt conversion with a selectivity to 1-octene of 10 m % and mixed internal octenes of 90 m %. Nitrogen gas was introduced downflow to a 1″×18″ 316 s

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: Ammonia gas was slowly bubbled through 1-methoxyoctane (50 mL) for 1 hour to form a saturated ammonia solution in 1-methoxyoctane. Analysis of ammonia in methoxyoctane indicated that the solution was saturated after 30 minutes of bubbling (15 min, 2372 mg NH3/L; 30 min, 3016 mg NH3/L; 60 min, 2924 mg NH3/L; 90 min, 3294 mg NH3/L). The NH3 saturated methoxyoctane solution was used as feed to the cracking reactor. The data are presented in Table 3. (NH3 helps to give higher conversion while maintaining high octene-1 selectivity.) of bubbling (15 min, 2372 mg NH3/L; 30 min, 3016 mg NH3/L; 60 min, 2924 mg NH3/L; 90 min, 3294 mg NH3/L)