N-亚硝基二异丙醇胺

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The DIPN conversion was 89.6 mol %, and the yield of 2,6-bis(2-hydroperoxy-2-propyl)naphthalene was 29.7 mol %. In addition, 2-(2-hydroxy-2-propyl)-6-(2-hydroperoxy-2-propyl)-naphthalene, 2,6-bis(2-hydroxy-2-propyl)naphthalene, 2-(2-hydroperoxy-2-propyl)-6-isopropylnaphthalene, and 2-(2-hydroxy-2-propyl)-6-isopropylnaphthalene were produced in yields of 11.9 mol %, 1.2 mol %, 35.3 mol %, and 7.9 mol %, respectively. The conversion of the isopropyl groups was 67.9 mol %.

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: The DIPN conversion was 92.8 mol %, and the yield of 2,6-bis(2-hydroperoxy-2-propyl)naphthalene was 33.4 mol %. In addition, 2-(2-hydroxy-2-propyl)-6-(2-hydroperoxy-2-propyl)-naphthalene, 2,6-bis(2-hydroxy-2-propyl)naphthalene, 2-(2-hydroperoxy-2-propyl)-6-isopropylnaphthalene, and 2-(2-hydroxy-2-propyl)-6-isopropylnaphthalene were produced in yields of 19.1 mol %, 3.3 mol %, 25.2 mol %, and 8.9 mol %, respectively. The conversion of the isopropyl groups was 75.8 mol %.