ethenoxymethylbenzene

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 45 g (0.25 equivalent) of a dicyclopentadiene skeleton phenolic resin (DPP-3H, special phenolic resin, available from Nippon Petrochemical Co., Ltd.), 38.1 g of vinylbenzyl chloride (CMS-AM; purity of 91%; 0.25 mol; m-/p-isomers: 50/50 wt % mixture; available from Seimi Chemical Co., Ltd.), 2.4 g of tetra-n-butylammonium bromide, 0.038 g of 2,4-dinitrophenol, and 200 g of methyl ethyl ketone were charged into a 1-liter four-necked flask equipped with a thermoregulator, a stirrer, a cooling condenser, and a dropping funnel and dissolved under stirring. 40 g of a 50 wt % aqueous solution of NaOH (NaOH purity of 95%, 0.475 mol) was added dropwise at 75° C. to the obtained solution over 20 minutes, and the whole was stirred at 75° C. for additional 4 hours. After the obtained reaction mixture was cooled to room temperature, the mixture was neutralized with 2N hydrochloric acid, and 100 g of toluene was added. An organic layer was then washed with 300 g of distilled water three times. After methyl ethyl ketone was removed under reduced pressure, a reaction product was precipitated in 300 ml of methanol to collect a solid matter through filtration, which was then dried at 50° C. in a vacuum oven to obtain a vinylbenzyl ether compound at an yield of 95%. The obtained compound is designated as Compound 19. equipped with a thermoregulator, a stirrer, a cooling condenser, and a dropping funnel dissolved the whole was stirred at 75° C. for additional 4 hours After the obtained reaction mixture was added An organic layer was then washed with 300 g of distilled water three times After methyl ethyl ketone was removed under reduced pressure a reaction product was precipitated in 300 ml of methanol to collect a solid matter through filtration, which was then dried at 50° C. in a vacuum oven

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 45 g (0.25 equivalent) of a dicyclopentadiene skeleton phenolic resin (DPP-3H, special phenolic resin, available from Nippon Petrochemicals Co., Ltd.), 38.1 g of vinylbenzyl chloride (CMS-AM; purity of 91%; 0.25 mol; m-/p-isomers: 50/50 wt % mixture; available from Seimi Chemical Co., Ltd.), 2.4 g of tetra-n-butylammonium bromide, 0.038 g of 2,4-dinitrophenol, and 200 g of methyl ethyl ketone were charged into a four-necked flask equipped with a thermoregulator, a stirrer, a cooling condenser, and a dropping funnel, and the mixture was dissolved under stirring. 40 g of a 50 wt % aqueous solution of NaOH (NaOH, 0.48 mol) was added dropwise at 75° C. to the obtained solution over 20 minutes, and a reaction was further carried out at 75° C. for 4 hours. The obtained mixture in the flask was neutralized with 2N hydrochloric acid, and 100 g of toluene was added. An organic layer was then washed with distilled water three times. After methyl ethyl ketone was distilled off under reduced pressure, a reaction product was precipitated in methanol to collect a solid matter through filtration, which was then dried at 50° C. in vacuum to obtain a vinylbenzyl ether compound. The obtained compound is designated as Compound 11. equipped with a thermoregulator, a stirrer, a cooling condenser, and a dropping funnel the mixture was dissolved was added An organic layer was then washed with distilled water three times After methyl ethyl ketone was distilled off under reduced pressure a reaction product was precipitated in methanol to collect a solid matter through filtration, which was then dried at 50° C. in vacuum

反应条件: temp:75.01; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: 45 g (0.25 equivalent) of dicyclopentadiene skeleton phenolic resin, DPP-3H (special phenolic resin manufactured by Nippon Petrochemical Co., Ltd.), 38.1 g of vinylbenzyl chloride CMS-AM (m-/p-isomers: 50/50 wt % mixture) (purity of 91%, 0.25 mol), 2.4 g of tetra-n-butylammonium bromide, 0.038 g of 2,4-dinitrophenol and 200 g of methyl ethyl ketone were charged into a 1-liter four-necked flask equipped with a thermoregulator, stirrer, cooling condenser and dropping funnel and dissolved under agitation, and 40 g of a 50 wt % aqueous solution of NaOH (NaOH purity of 95%, 0.475 mol) was added dropwise at 75° C. to the obtained solution over 20 minutes and further stirred at 75° C. for 4 hours. After the obtained reaction mixture was cooled to room temperature, it was neutralized with 2N hydrochloric acid, 100 g of toluene was added, and the organic layer was then washed three times with 300 g of distilled water. After methyl ethyl ketone was removed under reduced pressure, the reaction product was precipitated in 300 ml of methanol to collect solid matter through filtration, which was then dried at 50° C. in a vacuum oven to obtain a vinylbenzyl ether compound at a yield of 95%. This is designated as compound 3. equipped with a thermoregulator, stirrer cooling condenser was added dropwise at 75° C. to the obtained solution over 20 minutes After the obtained reaction mixture was cooled to room temperature was added the organic layer was then washed three times with 300 g of distilled water After methyl ethyl ketone was removed under reduced pressure the reaction product was precipitated in 300 ml of methanol to collect solid matter through filtration, which was then dried at 50° C. in a vacuum oven

反应条件: temp:0.00; pressure:0.00; stir:; See reaction.notes.procedure_details.

实验步骤: Ethyl vinyl ether was mixed in benzyl alcohol, to which was then added mercury acetate, and the mixture was stirred at room temperature for 12 hours. The reaction mixture was extracted with ethyl acetate and the ethyl acetate extract was washed with water, followed by distillation in vacuo to obtain benzyl vinyl ether. The reaction mixture was extracted with ethyl acetate the ethyl acetate extract was washed with water followed by distillation in vacuo